Vanadium Catalysis-Editors: Manas Sutradhar, Armando J L Pombeiro, José Armando L da Silva

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isbn: 978-1-83916-088-2
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Vanadium CatalysisEditors: Manas Sutradhar, Armando J L Pombeiro, José Armando L da Silva

Vanadium Catalysis.jpg

Publication details

https://doi.org/10.1039/9781839160882


Print publication date

12 Nov 2020

Copyright year

2021

Print ISBN

978-1-78801-857-9

PDF eISBN

978-1-83916-088-2

ePub eISBN

978-1-83916-089-9

About this book

Vanadium is one of the more abundant elements in the Earth’s crust and exhibits a wide range of oxidation states in its compounds making it potentially a more sustainable and more economical choice as a catalyst than the noble metals. A wide variety of reactions have been found to be catalysed by homogeneous, supported and heterogeneous vanadium complexes and the number of applications is growing fast.

Bringing together the research on the catalytic uses of this element into one essential resource, including theoretical perspectives on proposed mechanisms for vanadium catalysis and an overview of its relevance in biological processes, this book is a useful reference for industrial and academic chemists alike.

From the book series:
Catalysis Series


Author information

Manas Sutradhar is currently a researcher at the Centro de Química Estrutural, Instituto Superior Técnico, Universidade de Lisboa (ULisboa). Metal complexes with aroylhydrazones, oxidation catalysis, magnetic properties and biological activity study are the main fields of his work. The major contribution of his research work is in the areas of chemistry of oxidovanadium(IV/V) and non-oxido vanadium(IV) complexes in oxidation catalysis.

José Armando L. da Silva is an Assistant Professor at the Instituto Superior Técnico, Universidade de Lisboa (ULisboa). His research addresses on Bioinorganic Chemistry, mainly on biological roles of vanadium, homogeneous catalysis with models of metallobiomolecules and Prebiotic Chemistry.

Armando J. L. Pombeiro is Full Professor at the Instituto Superior Técnico, Universidade de Lisboa (ULisboa), Honorary Professor at Saint Petersburg State University, founder President of the College of Chemistry of ULisboa and immediate past President of Centro de Química Estrutural, Coordinator of its Coordination Chemistry and Catalysis group, and Director of the Catalysis and Sustainability (CATSUS) PhD program. He is Full Member of the Academy of Sciences of Lisbon, Fellow of the European Academy of Sciences and co-founder and former President of the Portuguese Electrochemical Society. His research addresses activation of small molecules with industrial, environmental or biological significance, including metal-mediated synthesis and catalysis (e.g., functionalization of alkanes), self-assembly of polynuclear and supramolecular structures, non-covalent interactions in synthesis, crystal engineering of coordination compounds, molecular electrochemistry and theoretical studies.

 Preliminary content


Front Matter

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Pages 1 - 6


Preface

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Pages 7 - 8


Contents

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Pages 9 - 21

Chapter 1

Introduction: Vanadium, Its Compounds and Applications

Manas Sutradhar, José Armando L. Da Silva and Armando J. L. Pombeiro

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Pages 1 - 11

Chapter 2

Amavadin and Related Complexes as Oxidation Catalysts

José Armando L. Da Silva, M. Fátima C. Guedes da Silva, Manas Sutradhar and Armando J. L. Pombeiro

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Pages 12 - 34

Chapter 3

Activating Hydroperoxides by Vanadium(V) Compounds

Jens Hartung

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Pages 35 - 71

Chapter 4

The Vanadate–Pyrazinecarboxylic Acid–Hydrogen Peroxide Reagent and Similar Systems for Efficient Oxidations with Peroxides

Georgiy B. Shul'pin and Lidia S. Shul'pina

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Pages 72 - 96

Chapter 5

Peroxo-vanadium Complexes as Sustainable Catalysts in Oxidations, Halogenations and Other Organic Transformations

F. Sabuzi, G. Pomarico, V. Conte and P. Galloni

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Pages 97 - 110

Chapter 6

Vanadium-scorpionate Catalysed Oxidations

L. M. D. R. S. Martins and A. J. L. Pombeiro

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Pages 111 - 121

Chapter 7

Vanadium-aroylhydrazone Catalysed Oxidations

Manas Sutradhar, Vladimir B. Arion, Tannistha Roy Barman and Armando J. L. Pombeiro

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Pages 122 - 143

Chapter 8

Vanadium-oxide Molecular Catalysts in Non-aqueous Solution

Y. Hayashi, M. Katayama and K. Ozutsumi

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Pages 144 - 164

Chapter 9

Catalysis by Oxometalates and Their Microheterogeneous Media

J. Lodh and S. Roy

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Pages 165 - 204

Chapter 10

Use of Vanadium Catalysts in Epoxidation and Sulphoxidation Reactions with Green Chemistry Criteria

Agustín Galindo, Antonio Pastor, Francisco Montilla and María del Mar Conejo

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Pages 205 - 240

Chapter 11

Supported Vanadium Catalysts: Heterogeneous Molecular Complexes, Electrocatalysis and Biomass Transformation

Cristina Freire, Clara Pereira, Bruno Jarrais, Diana Fernandes, Andreia Peixoto, Natália Cordeiro and Filipe Teixeira

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Pages 241 - 284

Chapter 12

Carbon-supported Vanadium Catalysis

Sónia A. C. Carabineiro, Luísa M. D. R. S. Martins and Manas Sutradhar

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Pages 285 - 320

Chapter 13

Molecularly Dispersed Vanadium Oxide: Structure–Reactivity Relationships for Reducibility and Hydrocarbon Oxidation

M. Olga Guerrero-Pérez, María V. Martínez-Huerta and Miguel A. Bañares

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Pages 321 - 339

Chapter 14

Vanadium Oxides in Photocatalysis, Including Bare Oxides and VOx-based Organic–Inorganic Nanocomposites

E. Benavente, J. Aliaga and G. González

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Pages 340 - 373

Chapter 15

Theoretical Mechanistic Analysis on Vanadium Oxidation Catalysis

M. L. Kuznetsov

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Pages 374 - 399

Chapter 16

Vanadium-catalyzed Olefin Oligomerization, Polymerization and Copolymerization

Shu Zhang and Wenjuan Zhang

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Pages 400 - 416

Chapter 17

Vanadium-catalysed Olefin Metathesis and Related Chemistry

Kotohiro Nomura

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Pages 417 - 445

Chapter 18

Vanadium-catalyzed Enantioselective C–C Bond-forming Reactions

Makoto Sako, Shinobu Takizawa and Hiroaki Sasai

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Pages 446 - 463

Chapter 19

Vanadium-induced Oxidative and Reductive Coupling

T. Amaya and T. Hirao

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Pages 464 - 482

Chapter 20

Vanadium-catalyzed Transformations of Selected Functional Groups

T. Moriuchi and T. Hirao

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Pages 483 - 496

Chapter 21

Vanadium Compounds as Indirect Activators of a G Protein-coupled Receptor

Duaa Althumairy, Heide A. Murakami, Rachel Colclough, B. George Barisas, Deborah A. Roess and Debbie C. Crans

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Pages 497 - 513

Chapter 22

Reductive Dioxygen Activation by Biomimetic Vanadium Complexes

C. Drouza and A. Keramidas

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Pages 514 - 534

Chapter 23

Vanadium in Catalytically Proceeding Natural Processes

Dieter Rehder

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Pages 535 - 547

Chapter 24

Vanadium Chloroperoxidases as Versatile Biocatalysts

Ron Wever, Rokus Renirie and Frank Hollmann

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Pages 548 - 563

Chapter 25

Vanadium Catalysis Relevant to Nitrogenase

Hung-Ruei Pan and Hua-Fen Hsu

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Pages 564 - 576

Subject Index

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Pages 577 - 588



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